: PHOSPHORUS-C_R1. SECTION 1: Identification of the substance/mixture and of the company/undertaking. SECTION 2: Hazards identification

Transcripción

1 PHOSPHORUS-C_R1 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Date of issue: 09/03/2017 Revision date: 09/03/2017 Supersedes: 25/03/2015 Version: 2.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Trade name Product group : Mixture : PHOSPHORUS-C_R1 : This SDS applies for any reference of this product Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec : In vitro diagnostics use Uses advised against 1.3. Details of the supplier of the safety data sheet SPINREACT, S.A.U. Ctra. Santa Coloma, 7 E Sant Esteve de Bas (GIRONA) - SPAIN T F spinreact@spinreact.com Emergency telephone number Emergency number : SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Flammable liquids Not classified Skin corrosion/irritation, Category 1A Serious eye damage/eye irritation, Category 1 Full text of H statements : see section 16 H314 H318 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) : Danger GHS05 : H314 - Causes severe skin burns and eye damage. : P280 - Wear eye protection, face shield, protective clothing, protective gloves. P501 - Dispose of contents in an appropriate container observing applicable local regulations 2.3. Other hazards This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures 12/12/2017 EN (English) SDS Ref.: BSSS16-R1 1/11

2 PHOSPHORUS-C_R1 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Sulphuric acid (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) N,N-dimethylformamide substance listed as REACH Candidate Sodium azide substance with a Community workplace exposure limit (CAS-No.) (EC-No.) (EC Index-No.) X (REACH-no) (CAS-No.) (EC-No.) (EC Index-No.) Met. Corr. 1, H290 Skin Corr. 1A, H Flam. Liq. 3, H226 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation), H332 Acute Tox. 4 (Inhalation:vapour), H332 Eye Irrit. 2, H319 Repr. 1B, H360D < 0.1 Acute Tox. 2 (Oral), H300 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Specific concentration limits: Name Product identifier Specific concentration limits Sulphuric acid (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) Full text of H-statements: see section 16 ( 5 =<C < 15) Eye Irrit. 2, H319 ( 5 =<C < 15) Skin Irrit. 2, H315 (C >= 15) Skin Corr. 1A, H314 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. : Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER/doctor. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor Most important symptoms and effects, both acute and delayed Symptoms/effects : Causes severe skin burns and eye damage Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture Fire hazard Hazardous decomposition products in case of fire : Not flammable. : nitrogen oxides (NOx) and sulphur oxides. Carbon dioxide. Carbon monoxide Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area. 12/12/2017 EN (English) SDS Ref.: BSSS16-R1 2/11

3 PHOSPHORUS-C_R1 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/ Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible products 7.3. Specific end use(s) : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. Collect all waste in suitable and labelled containers and dispose according to local legislation. : Provide good ventilation in process area to prevent formation of vapour. Do not breathe vapours. Avoid contact with skin, eyes and clothing. : Wash the contacted area thoroughly after handling. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. : Comply with applicable regulations. : Keep only in the original container in a cool, well ventilated place away from : Heat sources. Keep container closed when not in use. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Sulphuric acid ( ) EU Local name Sulphuric acid (mist) EU IOELV TWA (mg/m³) 0.05 mg/m³ Spain Local name Ácido sulfúrico Spain VLA-ED (mg/m³) 0.05 mg/m³ az,vli, s,d. Spain Notes az (Al seleccionar un método adecuado de control de la exposición, deben tomarse en consideración posibles limitaciones e interferencias que pueden surgir en presencia de otros compuestos de azufre), VLI (Agente químico para el que la U.E. estableció en su día un valor límite indicativo. Todos estos agentes químicos figuran al menos en una de las directivas de valores límite indicativos publicadas hasta ahora (ver Anexo C. Bibliografía). Los estados miembros disponen de un tiempo fijado en dichas directivas para su transposición a los valores límites de cada país miembro. Una vez adoptados, estos valores tienen la misma validez que el resto de los valores adoptados por el país), s (Esta sustancia tiene prohibida total o parcialmente su comercialización y uso como fitosanitario y/o como biocida. Para una información detallada acerca de las prohibiciones consúltese: Base de datos de productos biocidas: o=plaguicidas Base de datos de productos fitosanitarios stro/fichas/pdf/lista_sa.pdf), d (Véase UNE EN 481: Atmósferas en los puestos de trabajo. Definición de las fracciones por el tamaño de las partículas para la medición de aerosoles). N,N-dimethylformamide ( ) EU Local name N,N Dimethylformamide EU IOELV TWA (mg/m³) 15 mg/m³ EU IOELV TWA (ppm) 5 ppm EU IOELV STEL (mg/m³) 30 mg/m³ EU IOELV STEL (ppm) 10 ppm EU Notes skin Spain Local name N,N-Dimetilformamida Spain VLA-ED (mg/m³) 15 mg/m³ VLI,Vía dérmica, TR1A,VLB. 12/12/2017 EN (English) SDS Ref.: BSSS16-R1 3/11

4 PHOSPHORUS-C_R1 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 N,N-dimethylformamide ( ) Spain VLA-ED (ppm) 5 ppm VLI,Vía dérmica, TR1A,VLB. Spain VLA-EC (mg/m³) 30 mg/m³ VLI,Vía dérmica, TR1A,VLB. Spain VLA-EC (ppm) 10 ppm VLI,Vía dérmica, TR1A,VLB. Spain Notes VLI (Agente químico para el que la U.E. estableció en su día un valor límite indicativo. Todos estos agentes químicos figuran al menos en una de las directivas de valores límite indicativos publicadas hasta ahora (ver Anexo C. Bibliografía). Los estados miembros disponen de un tiempo fijado en dichas directivas para su transposición a los valores límites de cada país miembro. Una vez adoptados, estos valores tienen la misma validez que el resto de los valores adoptados por el país), Vía dérmica (Indica que, en las exposiciones a esta sustancia, la aportación por la vía cutánea puede resultar significativa para el contenido corporal total si no se adoptan medidas para prevenir la absorción. En estas situaciones, es aconsejable la utilización del control biológico para poder cuantificar la cantidad global absorbida del contaminante. Para más información véase el Apartado 5 de este documento), TR1B (Cuando las pruebas utilizadas para la clasificación procedan principalmente de datos en animales), VLB (Agente químico que tiene Valor Límite Biológico específico en este documento). Sodium azide ( ) EU Local name Sodium azide EU IOELV TWA (mg/m³) 0.1 mg/m³ EU IOELV STEL (mg/m³) 0.3 mg/m³ EU Notes Skin Spain Local name Azida de sodio (Aziduro de sodio; Trinitruro de sodio) Spain VLA-ED (mg/m³) 0.1 mg/m³ Vía dérmica, VLI Spain VLA-EC (mg/m³) 0.3 mg/m³ Vía dérmica, VLI Spain Notes vía dérmica, VLI 8.2. Exposure controls Personal protective equipment: Avoid all unnecessary exposure. Hand protection: Chemically resistant protective gloves Eye protection: Chemical goggles or face shield Skin and body protection: Wear suitable protective clothing Respiratory protection: Where excessive vapour may result, wear approved mask Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Colourless. Odour : Odorless. Odour threshold ph : <= 2 Relative evaporation rate (butylacetate=1) Melting point Freezing point 12/12/2017 EN (English) SDS Ref.: BSSS16-R1 4/11

5 PHOSPHORUS-C_R1 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : Non flammable. : Material highly soluble in water Other information SECTION 10: Stability and reactivity Reactivity Corrosive vapours Chemical stability Stable under recommended handling and storage conditions (see section 7) Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products nitrogen oxides (NOx) and sulphur oxides. Carbon dioxide. Carbon monoxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) N,N-dimethylformamide ( ) LD50 oral rat > 5.85 mg/kg (4 h) LD50 dermal rat > 3160 mg/kg LC50 inhalation rat (ppm) 3040 ppm Sodium azide ( ) LD50 oral rat LD50, oral, rabbit LD50, Inhalation, rat LD50, Dermal, rabbit Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity 27 mg/kg 10 mg/kg 37 mg/m³ 20 mg/kg : Causes severe skin burns and eye damage. ph: <= 2 : Causes serious eye damage. ph: <= 2 12/12/2017 EN (English) SDS Ref.: BSSS16-R1 5/11

6 PHOSPHORUS-C_R1 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 STOT-single exposure STOT-repeated exposure Aspiration hazard SECTION 12: Ecological information Toxicity Acute aquatic toxicity Chronic aquatic toxicity N,N-dimethylformamide ( ) LC50 fish mg/l (L. Macrochirus - 96 h) EC50 Daphnia 1 > 100 mg/l (Daphnia magna - 48 h) EC50 72h algae (1) > 1000 mg/l (P. Subcapitata - 72 h) ErC50 (algae) > 1000 mg/l (P. Subcapitata, 72h) Sodium azide ( ) LC50 fish mg/l (Lepomis macrochirus - 96 h) EC50 Daphnia mg/l (Daphnia pulex - 48 h) Persistence and degradability PHOSPHORUS-C_R1 Persistence and degradability Not established. N,N-dimethylformamide ( ) BOD (% of ThOD) 100 % ThOD (21 d) Bioaccumulative potential PHOSPHORUS-C_R1 Bioaccumulative potential N,N-dimethylformamide ( ) Log Pow Mobility in soil Results of PBT and vpvb assessment Not established. PHOSPHORUS-C_R1 This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII Component N,N-dimethylformamide ( ) Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Product/Packaging disposal recommendations Ecology - waste materials SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) : 3264 UN-No. (IMDG) : 3264 UN-No. (IATA) : 3264 UN-No. (ADN) : 3264 UN-No. (RID) : UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents in an appropriate container observing applicable local regulations. : Avoid release to the environment. : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. 12/12/2017 EN (English) SDS Ref.: BSSS16-R1 6/11

7 PHOSPHORUS-C_R1 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) Transport document description (IATA) Transport document description (ADN) Transport document description (RID) : Corrosive liquid, acidic, inorganic, n.o.s. : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. : UN 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Sulphuric acid mixture), 8, III, (E) : UN 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., 8, III : UN 3264 Corrosive liquid, acidic, inorganic, n.o.s., 8, III : UN 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., 8, III : UN 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., 8, III Transport hazard class(es) ADR Transport hazard class(es) (ADR) : 8 Danger labels (ADR) : 8 : IMDG Transport hazard class(es) (IMDG) : 8 Danger labels (IMDG) : 8 : IATA Transport hazard class(es) (IATA) : 8 Hazard labels (IATA) : 8 : ADN Transport hazard class(es) (ADN) : 8 Danger labels (ADN) : 8 : RID Transport hazard class(es) (RID) : 8 Danger labels (RID) : 8 : 12/12/2017 EN (English) SDS Ref.: BSSS16-R1 7/11

8 PHOSPHORUS-C_R1 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/ Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : III : III : III : III : III : No : No : No supplementary information available Special precautions for user - Overland transport Classification code (ADR) : C1 Special provisions (ADR) : 274 Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage : 5l : E1 : P001, IBC03, LP01, R001 : MP19 : T7 : TP1, TP28 : L4BN : AT Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) : V12 Hazard identification number (Kemler No.) : 80 Orange plates : Tunnel restriction code (ADR) : E - Transport by sea Special provisions (IMDG) : 223, 274 Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P001, LP01 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP1, TP28 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : A Stowage and handling (IMDG) : SW2 Properties and observations (IMDG) : Causes burns to skin, eyes and mucous membranes. - Air transport PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y841 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 852 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 856 CAO max net quantity (IATA) : 60L Special provisions (IATA) : A3 12/12/2017 EN (English) SDS Ref.: BSSS16-R1 8/11

9 PHOSPHORUS-C_R1 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 ERG code (IATA) : 8L - Inland waterway transport Classification code (ADN) : C1 Special provisions (ADN) : 274 Limited quantities (ADN) Excepted quantities (ADN) Carriage permitted (ADN) Equipment required (ADN) : 5 L : E1 : T Number of blue cones/lights (ADN) : 0 - Rail transport Classification code (RID) : PP, EP : C1 Special provisions (RID) : 274 Limited quantities (RID) Excepted quantities (RID) Packing instructions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) : 5L : E1 : P001, IBC03, LP01, R001 : MP19 : T7 Transport category (RID) : 3 Special provisions for carriage Packages (RID) Colis express (express parcels) (RID) : TP1, TP28 : L4BN : W12 : CE8 Hazard identification number (RID) : Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations The following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006: 3. Liquid substances or mixtures which are regarded as dangerous in Sulphuric acid - N,N-dimethylformamide accordance with Directive 1999/45/EC or are fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008 3(a) Substances or mixtures fulfilling the criteria for any of the following N,N-dimethylformamide hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F 3(b) Substances or mixtures fulfilling the criteria for any of the following Sulphuric acid - N,N-dimethylformamide - Sodium azide hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and (c) Substances or mixtures fulfilling the criteria for any of the following Sodium azide hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class Substances which appear in Part 3 of Annex VI to Regulation (EC) N,N-dimethylformamide No 1272/2008 classified as Toxic to Reproduction category 1A or 1B (Table 3.1) or Toxic to Reproduction category 1 or 2 (Table 3.2) and listed as follows: Reproductive toxicant category 1A adverse effects on sexual function and fertility or on development (Table 3.1) or Reproductive toxicant category 1 with R60 (May impair fertility) or R61 (May cause harm to the unborn child) (Table 3.2) listed in Appendix 5 Reproductive toxicant category 1B adverse effects on sexual function and fertility or on development (Table 3.1) or Reproductive toxicant category 2 with R60 (May impair fertility) or R61 (May cause harm to the unborn child) (Table 3.2) listed in Appendix 6 12/12/2017 EN (English) SDS Ref.: BSSS16-R1 9/11

10 PHOSPHORUS-C_R1 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/ Substances classified as flammable gases category 1 or 2, flammable liquids categories 1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric solids category 1, regardless of whether they appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or not. N,N-dimethylformamide Contains a substance on the REACH candidate list in concentration 0.1% or with a lower specific limit: N,N-dimethylformamide (EC , CAS ) Contains no REACH Annex XIV substances National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Indication of changes: Transport information. Section Changed item Change Comments 14 CLASSIFICATION ACCORDING ADR/RID/IMDG/IATA/ADN Modified Change of transport requirements Abbreviations and acronyms: EC50 Median effective concentration LC50 Median lethal concentration LD50 Median lethal dose vpvb Very Persistent and Very Bioaccumulative PBT Persistent Bioaccumulative Toxic Data sources Other information : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : None. Full text of H- and EUH-statements: Acute Tox. 2 (Oral) Acute toxicity (oral), Category 2 Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Acute Tox. 4 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 4 Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 3 Flammable liquids, Category 3 Met. Corr. 1 Corrosive to metals, Category 1 Repr. 1B Reproductive toxicity, Category 1B Skin Corr. 1A Skin corrosion/irritation, Category 1A H226 Flammable liquid and vapour. H290 May be corrosive to metals. H300 Fatal if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H360D May damage the unborn child. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]: Flam. Liq. Not classified Expert judgment Skin Corr. 1A H314 On basis of test data 12/12/2017 EN (English) SDS Ref.: BSSS16-R1 10/11

11 PHOSPHORUS-C_R1 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Eye Dam. 1 H318 On basis of test data SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 12/12/2017 EN (English) SDS Ref.: BSSS16-R1 11/11

12 PHOSPHORUS-C_R2 Safety Data Sheet A safety data sheet is not required for this product under Article 31 of REACH. This Product Safety Information Sheet has been created on a voluntary basis Date of issue: 01/04/2015 Revision date: 01/04/2015 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name Product group : Mixture : PHOSPHORUS-C_R2 : This SDS applies for any reference of this product Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec : In vitro diagnostics use Uses advised against 1.3. Details of the supplier of the safety data sheet SPINREACT, S.A.U. Ctra. Santa Coloma, 7 E Sant Esteve de Bas (GIRONA) - SPAIN T F spinreact@spinreact.com Emergency telephone number Emergency number : SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display No labelling applicable 2.3. Other hazards Other hazards not contributing to the classification : None under normal conditions. SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures This mixture does not contain any substances to be mentioned according to the criteria of section 3.2 of REACH annex II SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 12/12/2017 EN (English) SDS Ref.: BSSS16-R2 1/6

13 PHOSPHORUS-C_R2 Safety Data Sheet A safety data sheet is not required for this product under Article 31 of REACH. This Product Safety Information Sheet has been created on a voluntary basis 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Not expected to present a significant hazard under anticipated conditions of normal use. : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. : Keep only in the original container in a cool, well ventilated place away from : Heat sources. Keep container closed when not in use. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight. Sodium azide ( ) EU Local name Sodium azide EU IOELV TWA (mg/m³) 0.1 mg/m³ EU IOELV STEL (mg/m³) 0.3 mg/m³ EU Notes Skin Spain Local name Azida de sodio (Aziduro de sodio; Trinitruro de sodio) Spain VLA-ED (mg/m³) 0.1 mg/m³ Vía dérmica, VLI Spain VLA-EC (mg/m³) 0.3 mg/m³ Vía dérmica, VLI Spain Notes vía dérmica, VLI chloroform ( ) EU Local name Chloroform 12/12/2017 EN (English) SDS Ref.: BSSS16-R2 2/6

14 PHOSPHORUS-C_R2 Safety Data Sheet A safety data sheet is not required for this product under Article 31 of REACH. This Product Safety Information Sheet has been created on a voluntary basis chloroform ( ) EU IOELV TWA (mg/m³) 10 mg/m³ EU IOELV TWA (ppm) 2 ppm EU Notes Skin Spain Local name Triclorometano (Cloroformo) Spain VLA-ED (mg/m³) 10 mg/m³ Spain VLA-ED (ppm) 2 ppm Spain Notes r, vía dérmica, VLI Exposure controls Personal protective equipment: Avoid all unnecessary exposure. Hand protection: Wear protective gloves. Eye protection: Chemical goggles or safety glasses Respiratory protection: Wear appropriate mask Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Colourless. Odour : Odorless. Odour threshold ph : 7.8 Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) : Non flammable. Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Not established. 12/12/2017 EN (English) SDS Ref.: BSSS16-R2 3/6

15 PHOSPHORUS-C_R2 Safety Data Sheet A safety data sheet is not required for this product under Article 31 of REACH. This Product Safety Information Sheet has been created on a voluntary basis Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Not known when used appropiately Hazardous decomposition products No hazardous decomposition products known. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) Skin corrosion/irritation Additional information Serious eye damage/irritation Additional information Respiratory or skin sensitisation Additional information Germ cell mutagenicity Additional information Carcinogenicity Additional information Reproductive toxicity Additional information STOT-single exposure Additional information STOT-repeated exposure Additional information Aspiration hazard Additional information Potential adverse human health effects and symptoms SECTION 12: Ecological information Toxicity Acute aquatic toxicity Chronic aquatic toxicity ph: 7.8 : Based on available data, the classification criteria are not met ph: 7.8 : Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met Persistence and degradability PHOSPHORUS-C_R2 Persistence and degradability Bioaccumulative potential PHOSPHORUS-C_R2 Bioaccumulative potential Not established. Not established Mobility in soil Results of PBT and vpvb assessment 12/12/2017 EN (English) SDS Ref.: BSSS16-R2 4/6

16 PHOSPHORUS-C_R2 Safety Data Sheet A safety data sheet is not required for this product under Article 31 of REACH. This Product Safety Information Sheet has been created on a voluntary basis Other adverse effects Additional information : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) UN-No. (IMDG) UN-No. (IATA) UN-No. (ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available Special precautions for user - Overland transport No data available - Transport by sea No data available 12/12/2017 EN (English) SDS Ref.: BSSS16-R2 5/6

17 PHOSPHORUS-C_R2 Safety Data Sheet A safety data sheet is not required for this product under Article 31 of REACH. This Product Safety Information Sheet has been created on a voluntary basis - Air transport No data available - Inland waterway transport No data available - Rail transport No data available Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information A safety data sheet is not required for this product under Article 31 of REACH. This Product Safety Information Sheet has been created on a voluntary basis Data sources Other information : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : None. SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 12/12/2017 EN (English) SDS Ref.: BSSS16-R2 6/6

18 PHOSPHORUS_CAL Safety Data Sheet A safety data sheet is not required for this product under Article 31 of REACH. This Product Safety Information Sheet has been created on a voluntary basis Date of issue: 01/04/2015 Revision date: 01/04/2015 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name Product group : Mixture : PHOSPHORUS_CAL : This SDS applies for any reference of this product Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec : In vitro diagnostics use Uses advised against 1.3. Details of the supplier of the safety data sheet SPINREACT, S.A.U. Ctra. Santa Coloma, 7 E Sant Esteve de Bas (GIRONA) - SPAIN T F spinreact@spinreact.com Emergency telephone number Emergency number : SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display No labelling applicable 2.3. Other hazards Other hazards not contributing to the classification : None under normal conditions. SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures This mixture does not contain any substances to be mentioned according to the criteria of section 3.2 of REACH annex II SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 12/12/2017 EN (English) SDS Ref.: BSSS15-CAL 1/6

19 PHOSPHORUS_CAL Safety Data Sheet A safety data sheet is not required for this product under Article 31 of REACH. This Product Safety Information Sheet has been created on a voluntary basis 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Not expected to present a significant hazard under anticipated conditions of normal use. : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. : Keep only in the original container in a cool, well ventilated place away from : Heat sources. Keep container closed when not in use. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight. Sodium azide ( ) EU Local name Sodium azide EU IOELV TWA (mg/m³) 0.1 mg/m³ EU IOELV STEL (mg/m³) 0.3 mg/m³ EU Notes Skin Spain Local name Azida de sodio (Aziduro de sodio; Trinitruro de sodio) Spain VLA-ED (mg/m³) 0.1 mg/m³ Vía dérmica, VLI Spain VLA-EC (mg/m³) 0.3 mg/m³ Vía dérmica, VLI Spain Notes vía dérmica, VLI 12/12/2017 EN (English) SDS Ref.: BSSS15-CAL 2/6

20 PHOSPHORUS_CAL Safety Data Sheet A safety data sheet is not required for this product under Article 31 of REACH. This Product Safety Information Sheet has been created on a voluntary basis 8.2. Exposure controls Personal protective equipment: Avoid all unnecessary exposure. Hand protection: Wear protective gloves. Eye protection: Chemical goggles or safety glasses Respiratory protection: Wear appropriate mask Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Not established Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Not known when used appropiately Hazardous decomposition products : Liquid : Colourless. : Odorless. : Non flammable. No hazardous decomposition products known. 12/12/2017 EN (English) SDS Ref.: BSSS15-CAL 3/6

21 PHOSPHORUS_CAL Safety Data Sheet A safety data sheet is not required for this product under Article 31 of REACH. This Product Safety Information Sheet has been created on a voluntary basis SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) Skin corrosion/irritation Additional information Serious eye damage/irritation Additional information Respiratory or skin sensitisation Additional information Germ cell mutagenicity Additional information Carcinogenicity Additional information Reproductive toxicity Additional information STOT-single exposure Additional information STOT-repeated exposure Additional information Aspiration hazard Additional information Potential adverse human health effects and symptoms SECTION 12: Ecological information Toxicity Acute aquatic toxicity Chronic aquatic toxicity : Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met Persistence and degradability PHOSPHORUS_CAL Persistence and degradability Bioaccumulative potential PHOSPHORUS_CAL Bioaccumulative potential Not established. Not established Mobility in soil Results of PBT and vpvb assessment Other adverse effects Additional information : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) 12/12/2017 EN (English) SDS Ref.: BSSS15-CAL 4/6

22 PHOSPHORUS_CAL Safety Data Sheet A safety data sheet is not required for this product under Article 31 of REACH. This Product Safety Information Sheet has been created on a voluntary basis UN-No. (IMDG) UN-No. (IATA) UN-No. (ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available Special precautions for user - Overland transport No data available - Transport by sea No data available - Air transport No data available - Inland waterway transport No data available - Rail transport No data available Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations 12/12/2017 EN (English) SDS Ref.: BSSS15-CAL 5/6

23 PHOSPHORUS_CAL Safety Data Sheet A safety data sheet is not required for this product under Article 31 of REACH. This Product Safety Information Sheet has been created on a voluntary basis Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information A safety data sheet is not required for this product under Article 31 of REACH. This Product Safety Information Sheet has been created on a voluntary basis Data sources Other information : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : None. SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 12/12/2017 EN (English) SDS Ref.: BSSS15-CAL 6/6

24 FÓSFORO-C_R1 Ficha de datos de seguridad conforme al Reglamento (CE) N 1907/2006 (REACH), modificado por el Reglamento (UE) 2015/830 Fecha de emisión: 09/03/2017 Fecha de revisión: 09/03/2017 Reemplaza la ficha: 25/03/2015 Versión: 2.0 SECCIÓN 1: Identificación de la sustancia o la mezcla y de la sociedad o la empresa 1.1. Identificador del producto Forma del producto Nombre comercial Grupo de productos : Mezcla : FÓSFORO-C_R1 : Esta FDS aplica a cualquier referencia del producto Usos pertinentes identificados de la sustancia o de la mezcla y usos desaconsejados Usos pertinentes identificados Especificaciones de utilización industrial/profesional : Solo para diagnostico in vitro profesional Usos desaconsejados 1.3. Datos del proveedor de la ficha de datos de seguridad SPINREACT, S.A.U. Ctra. Santa Coloma, 7 E Sant Esteve de Bas (GIRONA) - SPAIN T F spinreact@spinreact.com Teléfono de emergencia Número de emergencia : SECCIÓN 2: Identificación de los peligros 2.1. Clasificación de la sustancia o de la mezcla Clasificación según reglamento (UE) No. 1272/2008 [CLP] Líquidos inflamables No clasificado Irritación o corrosión cutáneas, Categoría H314 1A Lesiones oculares graves o irritación ocular, H318 Categoría 1 Texto completo de las frases H: véase la Sección 16 Efectos adversos fisicoquímicos, para la salud humana y el medio ambiente 2.2. Elementos de la etiqueta Etiquetado según el Reglamento (CE) N 1272/2008 [CLP] Etiquetado adicional a mostrarclasificación(es) adicional(es) a mostrar Pictogramas de peligro (CLP) : Palabra de advertencia (CLP) Indicaciones de peligro (CLP) Consejos de prudencia (CLP) : Peligro GHS05 : H314 - Provoca quemaduras graves en la piel y lesiones oculares graves. : P280 - Llevar gafas de protección, máscara, prendas de protección, guantes de protección. P501 - Eliminar el contenido/recipiente en un contenedor adecuado siguiendo las regulaciones locales vigentes 2.3. Otros peligros Esta sustancia/mezcla no cumple los criterios PBT del anexo XIII del reglamento REACH Esta sustancia/mezcla no cumple los criterios mpmb del anexo XIII del reglamento REACH SECCIÓN 3: Composición/información sobre los componentes 3.1. Sustancias No aplicable 3.2. Mezclas 12/12/2017 ES (español) FDS Ref.: BSSS16-R1 1/11

25 FÓSFORO-C_R1 Ficha de datos de seguridad conforme al Reglamento (CE) N 1907/2006 (REACH), modificado por el Reglamento (UE) 2015/830 Nombre Identificador del producto % Clasificación según reglamento (UE) No. 1272/2008 [CLP] Ácido sulfúrico (N CAS) (N CE) (N Índice) (REACH-no) N,N-dimetilformamida en la lista de candidatas REACH (N,N-dimethylformamide) Azida sódica sustancia a la que se aplica un límite comunitario de exposición en el lugar de trabajo (N CAS) (N CE) (N Índice) X (REACH-no) (N CAS) (N CE) (N Índice) Met. Corr. 1, H290 Skin Corr. 1A, H314 0,1-0,5 Flam. Liq. 3, H226 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation), H332 Acute Tox. 4 (Inhalation:vapour), H332 Eye Irrit. 2, H319 Repr. 1B, H360D < 0,1 Acute Tox. 2 (Oral), H300 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Límites de concentración específicos: Nombre Identificador del producto Límites de concentración específicos Ácido sulfúrico (N CAS) (N CE) (N Índice) (REACH-no) Texto completo de las frases H: ver sección 16 SECCIÓN 4: Primeros auxilios 4.1. Descripción de los primeros auxilios Medidas de primeros auxilios general Medidas de primeros auxilios en caso de inhalación Medidas de primeros auxilios en caso de contacto con la piel Medidas de primeros auxilios en caso de contacto con los ojos Medidas de primeros auxilios en caso de ingestión 4.2. Principales síntomas y efectos, agudos y retardados Síntomas/efectos ( 5 =<C < 15) Eye Irrit. 2, H319 ( 5 =<C < 15) Skin Irrit. 2, H315 (C >= 15) Skin Corr. 1A, H314 : No administrar nada por vía oral a las personas en estado de inconsciencia. En caso de malestar consultar a un médico (mostrarle la etiqueta siempre que sea posible). : Transportar a la persona al aire libre y mantenerla en una posición que le facilite la respiración. Llamar inmediatamente a un CENTRO DE TOXICOLOGĺA/médico. : Quitar inmediatamente todas las prendas contaminadas. Aclararse la piel con agua/ducharse. Llamar inmediatamente a un CENTRO DE TOXICOLOGĺA/médico. : Aclarar cuidadosamente con agua durante varios minutos. Quitar las lentes de contacto, si lleva y resulta fácil. Seguir aclarando. Llamar inmediatamente a un CENTRO DE TOXICOLOGĺA/médico. : Enjuagarse la boca. NO provocar el vómito. Llamar inmediatamente a un CENTRO DE TOXICOLOGĺA/médico. : Provoca quemaduras graves en la piel y lesiones oculares graves Indicación de toda atención médica y de los tratamientos especiales que deban dispensarse inmediatamente Tratamiento sintomático. SECCIÓN 5: Medidas de lucha contra incendios 5.1. Medios de extinción Medios de extinción apropiados Medios de extinción no apropiados : Espuma. Polvo seco. Dióxido de carbono. Agua pulverizada. Arena. : No utilizar flujos de agua potentes Peligros específicos derivados de la sustancia o la mezcla Peligro de incendio Productos de descomposición peligrosos en caso de incendio : No inflamable Recomendaciones para el personal de lucha contra incendios Instrucciones para extinción de incendio Protección durante la extinción de incendios SECCIÓN 6: Medidas en caso de vertido accidental : óxidos de nitrógeno (NOx) y óxidos de azufre. Dióxido de carbono. Monóxido de carbono. : Enfriar los contenedores expuestos mediante agua pulverizada o nebulizada. Sea prudente a la hora de extinguir cualquier incendio de productos químicos. Evitar que las aguas residuales de extinción de incendios contaminen el medio ambiente. : No entrar en la zona de fuego sin el equipo de protección adecuado, incluida la protección respiratoria Precauciones personales, equipo de protección y procedimientos de emergencia Para el personal que no forma parte de los servicios de emergencia Procedimientos de emergencia : Evacuar el personal no necesario. 12/12/2017 ES (español) FDS Ref.: BSSS16-R1 2/11

26 FÓSFORO-C_R1 Ficha de datos de seguridad conforme al Reglamento (CE) N 1907/2006 (REACH), modificado por el Reglamento (UE) 2015/ Para el personal de emergencia Equipo de protección Procedimientos de emergencia : Proporcionar una protección adecuada a los equipos de limpieza. : Ventilar la zona Precauciones relativas al medio ambiente Evitar la penetración en alcantarillas y aguas potables. Advertir a las autoridades si el líquido penetra en sumideros o en aguas públicas. Evitar su liberación al medio ambiente Métodos y material de contención y de limpieza Procedimientos de limpieza 6.4. Referencia a otras secciones Ver la Sección 8. Control de exposición/protección individual. SECCIÓN 7: Manipulación y almacenamiento 7.1. Precauciones para una manipulación segura Precauciones para una manipulación segura Medidas de higiene 7.2. Condiciones de almacenamiento seguro, incluidas posibles incompatibilidades Medidas técnicas : Absorber inmediatamente el producto derramado mediante sólidos inertes como arcilla o tierra de diatomeas. Recoger el vertido. Almacenar alejado de otros materiales. Depositar todos los residuos en recipientes adecuados y etiquetados para su posterior eliminación en función de la reglamentación local. : Garantizar una buena ventilación de la zona de trabajo para evitar la formación de vapores. No respirar los vapores. Evitar el contacto con la piel, los ojos y la ropa. : Lavarse la zona afectada concienzudamente tras la manipulación. Lavarse las manos y otras zonas expuestas con un jabón suave y con agua antes de comer, beber y fumar o de abandonar el trabajo. : Respetar la normativa vigente. Condiciones de almacenamiento : Consérvese únicamente en el recipiente de origen, en lugar fresco y bien ventilado lejos de : Fuentes de calor. Mantener los envases cerrados cuando no se estén utilizando. Productos incompatibles 7.3. Usos específicos finales : Bases fuertes. Ácidos fuertes. SECCIÓN 8: Controles de exposición/protección individual 8.1. Parámetros de control Ácido sulfúrico ( ) UE Nombre local Sulphuric acid (mist) UE IOELV TWA (mg/m³) 0,05 mg/m³ España Nombre local Ácido sulfúrico España VLA-ED (mg/m³) 0,05 mg/m³ az,vli, s,d. España Notas az (Al seleccionar un método adecuado de control de la exposición, deben tomarse en consideración posibles limitaciones e interferencias que pueden surgir en presencia de otros compuestos de azufre), VLI (Agente químico para el que la U.E. estableció en su día un valor límite indicativo. Todos estos agentes químicos figuran al menos en una de las directivas de valores límite indicativos publicadas hasta ahora (ver Anexo C. Bibliografía). Los estados miembros disponen de un tiempo fijado en dichas directivas para su transposición a los valores límites de cada país miembro. Una vez adoptados, estos valores tienen la misma validez que el resto de los valores adoptados por el país), s (Esta sustancia tiene prohibida total o parcialmente su comercialización y uso como fitosanitario y/o como biocida. Para una información detallada acerca de las prohibiciones consúltese: Base de datos de productos biocidas: o=plaguicidas Base de datos de productos fitosanitarios stro/fichas/pdf/lista_sa.pdf), d (Véase UNE EN 481: Atmósferas en los puestos de trabajo. Definición de las fracciones por el tamaño de las partículas para la medición de aerosoles). N,N-dimetilformamida ( ) UE Nombre local N,N Dimethylformamide UE IOELV TWA (mg/m³) 15 mg/m³ 12/12/2017 ES (español) FDS Ref.: BSSS16-R1 3/11

27 FÓSFORO-C_R1 Ficha de datos de seguridad conforme al Reglamento (CE) N 1907/2006 (REACH), modificado por el Reglamento (UE) 2015/830 N,N-dimetilformamida ( ) UE IOELV TWA (ppm) 5 ppm UE IOELV STEL (mg/m³) 30 mg/m³ UE IOELV STEL (ppm) 10 ppm UE Notas skin España Nombre local N,N-Dimetilformamida España VLA-ED (mg/m³) 15 mg/m³ VLI,Vía dérmica, TR1A,VLB. España VLA-ED (ppm) 5 ppm VLI,Vía dérmica, TR1A,VLB. España VLA-EC (mg/m³) 30 mg/m³ VLI,Vía dérmica, TR1A,VLB. España VLA-EC (ppm) 10 ppm VLI,Vía dérmica, TR1A,VLB. España Notas VLI (Agente químico para el que la U.E. estableció en su día un valor límite indicativo. Todos estos agentes químicos figuran al menos en una de las directivas de valores límite indicativos publicadas hasta ahora (ver Anexo C. Bibliografía). Los estados miembros disponen de un tiempo fijado en dichas directivas para su transposición a los valores límites de cada país miembro. Una vez adoptados, estos valores tienen la misma validez que el resto de los valores adoptados por el país), Vía dérmica (Indica que, en las exposiciones a esta sustancia, la aportación por la vía cutánea puede resultar significativa para el contenido corporal total si no se adoptan medidas para prevenir la absorción. En estas situaciones, es aconsejable la utilización del control biológico para poder cuantificar la cantidad global absorbida del contaminante. Para más información véase el Apartado 5 de este documento), TR1B (Cuando las pruebas utilizadas para la clasificación procedan principalmente de datos en animales), VLB (Agente químico que tiene Valor Límite Biológico específico en este documento). Azida sódica ( ) UE Nombre local Sodium azide UE IOELV TWA (mg/m³) 0,1 mg/m³ UE IOELV STEL (mg/m³) 0,3 mg/m³ UE Notas Skin España Nombre local Azida de sodio (Aziduro de sodio; Trinitruro de sodio) España VLA-ED (mg/m³) 0,1 mg/m³ Vía dérmica, VLI España VLA-EC (mg/m³) 0,3 mg/m³ Vía dérmica, VLI España Notas vía dérmica, VLI 8.2. Controles de la exposición Equipo de protección individual: Evitar toda exposición innecesaria. Protección de las manos: Guantes de protección resistentes a los productos químicos Protección ocular: Gafas químicas o pantalla facial Protección de la piel y del cuerpo: Llevar ropa de protección adecuada Protección de las vías respiratorias: En caso de producción excesiva de vapores, utilizar una máscara apropiada Otros datos: No comer, beber ni fumar durante la utilización. SECCIÓN 9: Propiedades físicas y químicas 9.1. Información sobre propiedades físicas y químicas básicas Forma/estado : Líquido Color : Incoloro. 12/12/2017 ES (español) FDS Ref.: BSSS16-R1 4/11

28 FÓSFORO-C_R1 Ficha de datos de seguridad conforme al Reglamento (CE) N 1907/2006 (REACH), modificado por el Reglamento (UE) 2015/830 Olor Umbral olfativo : Inodoro. ph : <= 2 Grado de evaporación (acetato de butilo=1) Punto de fusión Punto de solidificación Punto de ebullición Punto de inflamación Temperatura de autoignición Temperatura de descomposición Inflamabilidad (sólido, gas) Presión de vapor Densidad relativa de vapor a 20 C Densidad relativa Solubilidad Log Pow Viscosidad, cinemática Viscosidad, dinámica Propiedades explosivas Propiedad de provocar incendios Límites de explosión 9.2. Otros datos SECCIÓN 10: Estabilidad y reactividad Reactividad Vapores corrosivos Estabilidad química : No inflamable. : Producto muy soluble en agua. Es estable bajo condiciones recomendadas de manejo y almacenamiento (ver seccion 7) Posibilidad de reacciones peligrosas No establecido Condiciones que deben evitarse Luz directa del sol. Temperaturas extremadamente elevadas o extremadamente bajas Materiales incompatibles Ácidos fuertes. Bases fuertes Productos de descomposición peligrosos óxidos de nitrógeno (NOx) y óxidos de azufre. Dióxido de carbono. Monóxido de carbono. SECCIÓN 11: Información toxicológica Información sobre los efectos toxicológicos Toxicidad aguda (oral) Toxicidad aguda (cutánea) Toxicidad aguda (inhalación) N,N-dimetilformamida ( ) DL50 oral rata > 5,85 mg/kg (4 h) DL50 cutánea rata > 3160 mg/kg CL50 inhalación rata (ppm) 3040 ppm Azida sódica ( ) DL50 oral rata DL50, oral, conejo DL50, Inhalación, rata DL50, Cutáneo, conejo Corrosión o irritación cutáneas 27 mg/kg 10 mg/kg 37 mg/m³ 20 mg/kg : Provoca quemaduras graves en la piel y lesiones oculares graves. ph: <= 2 12/12/2017 ES (español) FDS Ref.: BSSS16-R1 5/11

29 FÓSFORO-C_R1 Ficha de datos de seguridad conforme al Reglamento (CE) N 1907/2006 (REACH), modificado por el Reglamento (UE) 2015/830 Lesiones oculares graves o irritación ocular Sensibilización respiratoria o cutánea Mutagenicidad en células germinales Carcinogenicidad Toxicidad para la reproducción : Provoca lesiones oculares graves. ph: <= 2 Toxicidad específica en determinados órganos (STOT) exposición única Toxicidad específica en determinados órganos (STOT) exposición repetida Peligro por aspiración SECCIÓN 12: Información ecológica Toxicidad Toxicidad acuática aguda Toxicidad acuática crónica N,N-dimetilformamida ( ) CL50 peces mg/l (L. Macrochirus - 96 h) CE50 Daphnia 1 > 100 mg/l (Daphnia magna - 48 h) EC50 72h algae 1 > 1000 mg/l (P. Subcapitata - 72 h) ErC50 (algas) > 1000 mg/l (P. Subcapitata, 72h) Azida sódica ( ) CL50 peces 1 0,68 mg/l (Lepomis macrochirus - 96 h) CE50 Daphnia 1 4,2 mg/l (Daphnia pulex - 48 h) Persistencia y degradabilidad FÓSFORO-C_R1 Persistencia y degradabilidad No establecido. N,N-dimetilformamida ( ) DBO (% de DTO) 100 % DThO (21 d) Potencial de bioacumulación FÓSFORO-C_R1 Potencial de bioacumulación N,N-dimetilformamida ( ) Log Pow -0, Movilidad en el suelo Resultados de la valoración PBT y mpmb No establecido. FÓSFORO-C_R1 Esta sustancia/mezcla no cumple los criterios PBT del anexo XIII del reglamento REACH Esta sustancia/mezcla no cumple los criterios mpmb del anexo XIII del reglamento REACH Componente N,N-dimetilformamida ( ) Otros efectos adversos SECCIÓN 13: Consideraciones relativas a la eliminación Métodos para el tratamiento de residuos Recomendaciones para la eliminación de productos/envases Ecología - residuos Esta sustancia/mezcla no cumple los criterios PBT del anexo XIII del reglamento REACH Esta sustancia/mezcla no cumple los criterios mpmb del anexo XIII del reglamento REACH : Destruir cumpliendo las condiciones de seguridad exigidas por la legislación local/nacional. Eliminar el contenido/recipiente en un contenedor adecuado siguiendo las regulaciones locales vigentes. : Evitar su liberación al medio ambiente. 12/12/2017 ES (español) FDS Ref.: BSSS16-R1 6/11

30 FÓSFORO-C_R1 Ficha de datos de seguridad conforme al Reglamento (CE) N 1907/2006 (REACH), modificado por el Reglamento (UE) 2015/830 SECCIÓN 14: Información relativa al transporte Según los requisitos de ADR / RID / IMDG / IATA / ADN Número ONU N ONU (ADR) : 3264 N ONU (IMDG) : 3264 N ONU (IATA) : 3264 N ONU (ADN) : 3264 N ONU (RID) : Designación oficial de transporte de las Naciones Unidas Designación oficial de transporte (ADR) Designación oficial de transporte (IMDG) Designación oficial de transporte (IATA) Designación oficial de transporte (ADN) Designación oficial de transporte (RID) Descripción del documento del transporte (ADR) Descripción del documento del transporte (IMDG) Descripción del documento del transporte (IATA) Descripción del documento del transporte (ADN) Descripción del documento del transporte (RID) Clase(s) de peligro para el transporte ADR Clase(s) de peligro para el transporte (ADR) : 8 Etiquetas de peligro (ADR) : 8 : LÍQUIDO CORROSIVO, ÁCIDO, INORGÁNICO, N.E.P. : LÍQUIDO CORROSIVO, ÁCIDO, INORGÁNICO, N.E.P. : Corrosive liquid, acidic, inorganic, n.o.s. : LÍQUIDO CORROSIVO, ÁCIDO, INORGÁNICO, N.E.P. : LÍQUIDO CORROSIVO, ÁCIDO, INORGÁNICO, N.E.P. : UN 3264 LÍQUIDO CORROSIVO, ÁCIDO, INORGÁNICO, N.E.P. (Mezcla de ácido sulfúrico), 8, III, (E) : UN 3264 LÍQUIDO CORROSIVO, ÁCIDO, INORGÁNICO, N.E.P., 8, III : UN 3264 Corrosive liquid, acidic, inorganic, n.o.s., 8, III : UN 3264 LÍQUIDO CORROSIVO, ÁCIDO, INORGÁNICO, N.E.P., 8, III : UN 3264 LÍQUIDO CORROSIVO, ÁCIDO, INORGÁNICO, N.E.P., 8, III : IMDG Clase(s) de peligro para el transporte (IMDG) : 8 Etiquetas de peligro (IMDG) : 8 : IATA Clase(s) de peligro para el transporte (IATA) : 8 Etiquetas de peligro (IATA) : 8 : ADN Clase(s) de peligro para el transporte (ADN) : 8 Etiquetas de peligro (ADN) : 8 12/12/2017 ES (español) FDS Ref.: BSSS16-R1 7/11

31 FÓSFORO-C_R1 Ficha de datos de seguridad conforme al Reglamento (CE) N 1907/2006 (REACH), modificado por el Reglamento (UE) 2015/830 : RID Clase(s) de peligro para el transporte (RID) : 8 Etiquetas de peligro (RID) : 8 : Grupo de embalaje Grupo de embalaje (ADR) Grupo de embalaje (IMDG) Grupo de embalaje (IATA) Grupo de embalaje (ADN) Grupo de embalaje (RID) Peligros para el medio ambiente Peligroso para el medio ambiente Contaminante marino Otros datos : III : III : III : III : III : No : No : No se dispone de información adicional Precauciones particulares para los usuarios - Transporte por vía terrestre Código de clasificación (ADR) : C1 Disposiciones especiales (ADR) : 274 Cantidades limitadas (ADR) Cantidades exceptuadas (ADR) Instrucciones de embalaje (ADR) Disposiciones particulares relativas al embalaje común (ADR) Instrucciones para cisternas portátiles y contenedores para granel (ADR) Disposiciones especiales para cisternas portátiles y contenedores para granel (ADR) Código cisterna (ADR) Vehículo para el transporte en cisterna : 5l : E1 : P001, IBC03, LP01, R001 : MP19 : T7 : TP1, TP28 : L4BN : AT Categoría de transporte (ADR) : 3 Disposiciones especiales de transporte - Bultos (ADR) : V12 N Peligro (código Kemler) : 80 Panel naranja : Código de restricción en túneles (ADR) : E - Transporte marítimo Disposiciones especiales (IMDG) : 223, 274 Cantidades limitadas (IMDG) : 5 L Cantidades exceptuadas (IMDG) : E1 Instrucciones de embalaje (IMDG) : P001, LP01 Instrucciones de embalaje GRG (IMDG) : IBC03 Instrucciones para cisternas (IMDG) : T7 12/12/2017 ES (español) FDS Ref.: BSSS16-R1 8/11